82,848 research outputs found

    Ecofriendly Synthesis in Aqueous Medium: An Expeditious Approach to New N,N-Diethyl Amide Bearing Benzenemethanesulfonamides

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    An highly expeditious synthetic approach for the synthesis of benzenemethanesulfonamides (1a-k) and their new corresponding N,N-diethyl substituted amido moieties (2a-k) has been achieved in aqueous medium at room tem-perature. The reaction condition was thoroughly optimized thereby allowing significant rate enhancement and resulting into excellent yields. The chemical structures of the successful candidates were confirmed using elemental analytical and spectroscopic data such as IR, 1H NMR, 13C NMR and some selected mass spectral dat

    Synthesis and Antibacterial Activity of N,N-Diethyl-3-substituted-2-(4-methyl-phenylsulfonamido)alkanamides and their Arylsulfonamide Precursors

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    A series of N,N-diethyl-3-substituted-2-(4-methylphenylsulfon amido)alkanamides (8a-k) and their arylsulfonamide precursors (7a-k) have been synthesized via facile approach. The chemical structures of the synthesized compounds were confirmed by analytical data and spectroscopic means. The in vitro antibacterial screening of these compounds along with streptomycin, showed N,N-diethyl-2-(4-methylphenylsulfonamido) -3-phenylpropanamide (8j) to be the most active agent on Escherichia coli at MIC of 12.5 ÎĽg/mL and on Staphylococcus aureus at MIC of 25 ÎĽg/mL

    Non-Relativistic Limit of Dirac Equations in Gravitational Field and Quantum Effects of Gravity

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    Based on unified theory of electromagnetic interactions and gravitational interactions, the non-relativistic limit of the equation of motion of a charged Dirac particle in gravitational field is studied. From the Schrodinger equation obtained from this non-relativistic limit, we could see that the classical Newtonian gravitational potential appears as a part of the potential in the Schrodinger equation, which can explain the gravitational phase effects found in COW experiments. And because of this Newtonian gravitational potential, a quantum particle in earth's gravitational field may form a gravitationally bound quantized state, which had already been detected in experiments. Three different kinds of phase effects related to gravitational interactions are discussed in this paper, and these phase effects should be observable in some astrophysical processes. Besides, there exists direct coupling between gravitomagnetic field and quantum spin, radiation caused by this coupling can be used to directly determine the gravitomagnetic field on the surface of a star.Comment: 12 pages, no figur

    Colective Effects from Induced Behaviour

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    We present a solvable model for describing quantitatively situations where the individual behaviour of agents in a group "percolates" to collective behaviour of the group as a whole as a result of mutual influence between the agents.Comment: 6 pages, 6 figures, EPJ macro

    A Differential Turbo Detection Aided Sphere Packing Modulated Space-Time Coding Scheme

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    A signal construction method that combines orthogonal design with sphere packing has recently shown useful performance improvements over the conventional orthogonal design. In this contribution, we extend this concept and propose a novel Sphere Packing (SP) modulated differential Space-Time Block Coded (DSTBC) scheme, referred to here as (DSTBC-SP), which shows performance advantages over conventional DSTBC schemes. We also demonstrate that the performance of DSTBC-SP systems can be further improved by concatenating sphere packing aided modulation with channel coding and performing SP-symbol-to bit demapping as well as channel decoding iteratively. We also investigate the convergence behaviour of this concatenated scheme with the aid of Extrinsic Information Transfer (EXIT) Charts. The proposed turbo-detected DSTBC-SP scheme exhibits a ’turbo-cliff’ at Eb/N0 = 6dB and provides Eb/N0 gains of 23.7dB and 1.7dB at a BER of 10?5 over an equivalent-throughput uncoded DSTBC-SP scheme and a turbo-detected QPSK modulated DSTBC scheme, respectively
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